Effect on solvent polarity and concentration on the photo transformation of 6-nitro BIPS

S. Nazri, M. A. Malek, M. T. Zainuddin, N. M. Islam, Z. Wahid
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Abstract

Polar and non-polar solvents; ethanol and toluene respectively were used to dissolve and investigate the photochromism behavior of 6-nitro BIPS at different solvent concentration. Absorption spectra of 6-nitro BIPS in low concentration solvent were arising to absorption peak of 530nm and 600nm after UV irradiation for ethanol and toluene respectively. At high concentration solvent of 6-nitro BIPS, the absorption spectra did not present any changes on absorption peak after UV irradiation whereas the absorption peak was remains at 530nm for ethanol and no absorption peak appeared for toluene. Shifting of 6-nitro BIPS wavelength spectrum from 530nm for dilution in ethanol to 600nm for dilution in toluene in low concentration solvent was observed and investigated.
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溶剂极性和浓度对6-硝基BIPS光转化的影响
极性和非极性溶剂;分别用乙醇和甲苯溶解6-硝基BIPS,考察其在不同溶剂浓度下的光致变色行为。6-硝基BIPS在低浓度溶剂中对乙醇和甲苯的紫外辐射分别在530nm和600nm处出现吸收峰。在6-硝基BIPS的高浓度溶剂中,紫外辐照后吸收光谱的吸收峰没有变化,而乙醇的吸收峰保持在530nm处,甲苯的吸收峰没有出现。观察并研究了6-硝基BIPS在低浓度溶剂中从530nm稀释乙醇到600nm稀释甲苯的波长变化。
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