{"title":"Rotational Analysis of the Rydberg Spectrum of Water","authors":"M. Child, R. D. Gilbert, C. Jungen","doi":"10.1155/LC.11.253","DOIUrl":null,"url":null,"abstract":"Two techniques for rotational analysis of the nd←1b1 Rydberg spectra of H2O and D2O are discussed—a \nCoriolis coupled asymmetric top model for the room temperature 3d←1b1 cluster, and an extension of \nmultichannel quantum defect theory to asymmetric tops, which is applied to recent jet cooled photoionization \nspectra of the nd←1b1 series converging to the (100) vibrational levels of H2O","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"39 10","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Laser Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/LC.11.253","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
Two techniques for rotational analysis of the nd←1b1 Rydberg spectra of H2O and D2O are discussed—a
Coriolis coupled asymmetric top model for the room temperature 3d←1b1 cluster, and an extension of
multichannel quantum defect theory to asymmetric tops, which is applied to recent jet cooled photoionization
spectra of the nd←1b1 series converging to the (100) vibrational levels of H2O
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