Powder metallurgy fabrication of palladium contact alloys

L. L. Bourguignon, D. P. Agarwal, R. German, S. Farooq, S. Lin
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Abstract

The authors have combined some novel processing approaches to synthesize a high-performance material using powder metallurgy. A basic Pd-Ag-Cu composition was modified with metalloid additions to attain a fine grain size in combination with rapid solidification techniques. The internal grain structure was ideal for supersolidus sintering, having a dendritic arm spacing on the order of 1 mu m. The result is a fully dense alloy with attractive properties for electrical contact applications, including good conductivity, strength, wear, and corrosion resistance, comparable to or better than traditionally formed palladium-gold-silver-copper alloys. The addition of metalloids to the basic ternary system optimizes properties such as hardness and aids sinterability; yet the alloy can be fabricated without additional expense.<>
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钯接触合金的粉末冶金制备
作者结合了几种新的加工方法,采用粉末冶金技术合成了高性能材料。结合快速凝固技术,用类金属添加剂修饰了一种碱性的Pd-Ag-Cu组合物,以获得细晶粒尺寸。内部晶粒结构是超固体烧结的理想选择,其枝晶臂间距约为1 μ m。其结果是一种完全致密的合金,具有吸引电接触应用的性能,包括良好的导电性、强度、磨损和耐腐蚀性,可与传统形成的钯金银铜合金相媲美或更好。在基本三元体系中添加类金属可以优化硬度等性能,并有助于烧结;然而,这种合金可以在没有额外费用的情况下制造出来。
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