Synthesis of Mg/sub 2/Si/sub 1-x/Ge/sub x/ thermoelectric compound by solid phase reaction

L.M. Zhang, Y.G. Leng, H.Y. Jiang, L.D. Chen, T. Hirai
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引用次数: 1

Abstract

By two-stage solid phase reaction, a series of Mg/sub 2/Si/sub 1-x/Ge/sub x/ continuous solid solutions were successfully synthesized at low temperature (823 K) for the first time. The product was single-phased without any oxide or carbide and the particle size was substantially reduced than that of the raw powders. X-ray diffraction techniques were used to explore the products' phases and DTA to the changing tendency of heat quantity during the solid phase reaction. The influence of Ge substitution to Mg/sub 2/Si/sub 1-x/Ge/sub x/ was illustrated by the changes of lattice parameter and the existence of the complete solid solubility between Mg/sub 2/Si and Mg/sub 2/Ge was established, too.
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固相反应合成Mg/sub - 2/Si/sub -x/Ge/sub -x/热电化合物
通过两段固相反应,首次在低温(823 K)条件下成功合成了Mg/sub 2/Si/sub 1-x/Ge/sub x系列连续固溶体。该产品为单相,不含任何氧化物和碳化物,颗粒尺寸比原粉大大减小。采用x射线衍射技术对产物的物相进行了研究,并对固相反应过程中热的变化趋势进行了差热分析。通过晶格参数的变化说明了Ge取代对Mg/sub - 2/Si/sub - 1-x/Ge/sub -x/的影响,并证实了Mg/sub - 2/Si与Mg/sub - 2/Ge之间存在完全固溶性。
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