Realization of an in-situ Fluorescence & Raman Spectroscopy Setup for studying Quantum Dot Films

Jurgen Dijkema
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Abstract

A new experimental setup for studying charge transfer in Quantum Dot (QD) films has been designed, built and tested. The setup combines three spectroscopic methods; Raman, Fluorescence and Absorption Spectroscopy. First data on a Cadmium Selenide (CdSe) films reveals that radiative emission quenches while charging, attributed to Auger-decay. When fully discharged, the emission remains partly quenched, indicating that not all electrons are removed. Since charge transfer is a fundamental process in solar cells, the setup could be essential for designing and optimizing cost efficient future QD based solar cells.
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用于研究量子点薄膜的原位荧光和拉曼光谱装置的实现
设计、建立并测试了一种研究量子点(QD)薄膜中电荷转移的实验装置。该装置结合了三种光谱方法;拉曼,荧光和吸收光谱。在硒化镉(CdSe)薄膜上的第一个数据显示,在充电时辐射发射淬灭,归因于俄歇衰变。当完全放电时,发射仍然部分淬灭,表明并非所有电子都被移除。由于电荷转移是太阳能电池的基本过程,因此该装置对于设计和优化未来基于量子点的低成本太阳能电池至关重要。
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