Far-infrared spectroscopy of hydrogen bonding in nucleobases, nucleosides, and nucleotides

B. Fischer, M. Walther, P. Jepsen
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引用次数: 7

Abstract

The far-infrared dielectric properties of organic acids and bases in the condensed phase are dominated by hydrogen bonding between the individual molecules. We have investigated the dielectric properties of nucleobases, nucleosides, and nucleotides. We find that at cold temperatures distinct vibrational modes are present in the frequency range 0.1-4 THz. These modes originate from ordered hydrogen bonds between the molecules.
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核碱基、核苷和核苷酸中氢键的远红外光谱
在缩合相中,有机酸和有机碱的远红外介电性能主要受单个分子间氢键的影响。我们研究了核碱基、核苷和核苷酸的介电性质。我们发现在低温下,在0.1-4太赫兹的频率范围内存在不同的振动模式。这些模式源于分子间有序的氢键。
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