T. Minakova, N. Eremina, S. Mjakin, V. Bakhmetyev, M. Sychov, L. Svatovskaya, Dmitry I. Dolzhenko, A. Sychova
{"title":"Dispersity and Surface Characterization of Yttrium Vanadate and Phosphate Based Luminescent Phosphors","authors":"T. Minakova, N. Eremina, S. Mjakin, V. Bakhmetyev, M. Sychov, L. Svatovskaya, Dmitry I. Dolzhenko, A. Sychova","doi":"10.1109/EEXPOLYTECH.2018.8564374","DOIUrl":null,"url":null,"abstract":"The surface properties of Eu(III)-activated yttrium vanadate, yttrium phosphate and mixed yttrium vanadate-phosphate phosphors with different europium content synthesized via self-propagating high temperature synthesis are studied by low temperature nitrogen adsorption, scanning electron microscopy, aqueous slurry pH measurements and adsorption of acid-base indicators. Among the materials synthesized under similar conditions, phosphate based phosphors possess with a significantly more acidic surface (due to the presence of Lewis acidic centers probably corresponding to phosphorous atoms) and coarse dispersity compared with vanadate analogs, while mixed vanadate-phosphate compounds feature with the most fine dispersity.","PeriodicalId":296618,"journal":{"name":"2018 IEEE International Conference on Electrical Engineering and Photonics (EExPolytech)","volume":"218 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"2018 IEEE International Conference on Electrical Engineering and Photonics (EExPolytech)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/EEXPOLYTECH.2018.8564374","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The surface properties of Eu(III)-activated yttrium vanadate, yttrium phosphate and mixed yttrium vanadate-phosphate phosphors with different europium content synthesized via self-propagating high temperature synthesis are studied by low temperature nitrogen adsorption, scanning electron microscopy, aqueous slurry pH measurements and adsorption of acid-base indicators. Among the materials synthesized under similar conditions, phosphate based phosphors possess with a significantly more acidic surface (due to the presence of Lewis acidic centers probably corresponding to phosphorous atoms) and coarse dispersity compared with vanadate analogs, while mixed vanadate-phosphate compounds feature with the most fine dispersity.