Dispersity and Surface Characterization of Yttrium Vanadate and Phosphate Based Luminescent Phosphors

T. Minakova, N. Eremina, S. Mjakin, V. Bakhmetyev, M. Sychov, L. Svatovskaya, Dmitry I. Dolzhenko, A. Sychova
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引用次数: 1

Abstract

The surface properties of Eu(III)-activated yttrium vanadate, yttrium phosphate and mixed yttrium vanadate-phosphate phosphors with different europium content synthesized via self-propagating high temperature synthesis are studied by low temperature nitrogen adsorption, scanning electron microscopy, aqueous slurry pH measurements and adsorption of acid-base indicators. Among the materials synthesized under similar conditions, phosphate based phosphors possess with a significantly more acidic surface (due to the presence of Lewis acidic centers probably corresponding to phosphorous atoms) and coarse dispersity compared with vanadate analogs, while mixed vanadate-phosphate compounds feature with the most fine dispersity.
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钒酸钇和磷酸盐基发光荧光粉的分散性和表面表征
采用低温氮吸附、扫描电镜、水浆pH测定和酸碱指示剂吸附等方法,研究了自蔓延高温合成的不同铕含量的Eu(III)活化钒酸钇、磷酸钇和混合钒酸钇-磷酸荧光粉的表面性质。在相似条件下合成的材料中,磷酸盐基荧光粉的表面酸性明显更强(由于存在Lewis酸性中心,可能与磷原子相对应),分散性较钒酸盐类似物较粗,而钒酸-磷酸盐混合化合物的分散性最精细。
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