Glass ceramics with ferroelectric crystalline phases

M. Letz, M.J. Davis, B. Hoppe
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Abstract

Obtaining a glass ceramic via devitrification of a fully amorphous glass phase leads to a pore-free material, in which crystallites with their ferroelectric phase are embedded in a residual glass matrix. This matrix in turn forms a close-to-ideal dielectric. Such a structure offers, in principle, several advantages over conventional sintered ceramics, particularly with respect to ageing and fatigue. We show examples of ferroelectric glass ceramics in which the composition of the ferroelectric phase as well as the size of the crystallites are varied in a systematic way. The dielectric and structural properties are discussed in detail.
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具有铁电晶体相的玻璃陶瓷
通过完全非晶玻璃相的反氮化得到玻璃陶瓷,导致无孔材料,其中具有铁电相的晶体嵌入在残余的玻璃基体中。这个矩阵反过来形成一个接近理想的电介质。原则上,这种结构提供了优于传统烧结陶瓷的几个优点,特别是在老化和疲劳方面。我们展示了铁电玻璃陶瓷的例子,其中铁电相的组成以及晶体的大小以系统的方式变化。详细讨论了材料的介电性能和结构性能。
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