Effect of Zn addition on thermoelectric properties of Zn/sub 4/Sb/sub 3/ synthesized by direct hot pressing

S. Ur, J. Kwon, Il-ho Kim, P. Nash, Young‐Geun Lee, S. Kweon, T. Hong
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引用次数: 1

Abstract

Powder metallurgy was used to produce polycrystalline specimens of single phase /spl epsi/-Zn/sub 4/Sb/sub 3/ and two-phase specimens of /spl epsi/-Zn/sub 4/Sb/sub 3/ (majority phase) and Zn. The effect of excess Zn addition to the stoichiometry of Zn/sub 4/Sb/sub 3/ was investigated on the thermoelectric properties as well as mechanical properties in the alloy system. The room-temperature thermoelectric properties of our single phase Zn/sub 4/Sb/sub 3/ alloys are comparable to those reported by other researchers on samples prepared by hot pressing of ingot melted alloy powders. It is shown that the addition of Zn enhances the mechanical properties while sacrificing the thermoelectric properties.
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添加Zn对直接热压合成Zn/sub 4/Sb/sub 3/热电性能的影响
采用粉末冶金法制备了/spl epsi/-Zn/sub 4/Sb/sub 3/单相多晶试样和/spl epsi/-Zn/sub 4/Sb/sub 3/(多数相)和Zn两相试样。研究了过量锌加入Zn/sub 4/Sb/sub 3/的化学计量对合金体系热电性能和力学性能的影响。我们的单相Zn/sub 4/Sb/sub 3/合金的室温热电性能与其他研究人员用铸锭熔化合金粉末热压法制备的样品相当。结果表明,锌的加入在牺牲热电性能的同时提高了材料的力学性能。
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