Optical Fiber Tip Functionalized by Colloidal Photonic Crystal and Gold Nano-Particles for SERS Sensing

L. Sansone, M. Pannico, P. Musto, S. Campopiano, M. Giordano, A. Iadicicco
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Abstract

This work explores metal-dielectric colloidal crystal (MDCC) structures as SERS sensing layer. The MDCCs are fabricated directly onto optical fiber tip surface by successive depositions of PS Colloidal Crystal (CC) and Au NanoParticles. The fiber device is explored as remote SERS probe in optrode configuration. The MDCC permits to combine localized surface plasmon resonance (LSPR) of noble metallic nanoparticles and photonic bandgap (PBG) of colloidal type photonic crystals (PhCs). For the sensing test, the fiber probes were immersed in a 100μM aqueous solution of Rhodamine (R6G). Then, preliminary SERS results were retrieved by a Labspec Aramis confocal Raman spectrometer.
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胶体光子晶体和金纳米粒子功能化光纤尖端用于SERS传感
本研究探索了金属-介电胶体晶体(MDCC)结构作为SERS传感层。通过PS胶体晶体(CC)和金纳米粒子的连续沉积,直接在光纤尖端表面制备了mdcc。将光纤器件作为光极结构的远程SERS探针进行了研究。MDCC允许贵金属纳米粒子的局部表面等离子体共振(LSPR)和胶体型光子晶体(PhCs)的光子带隙(PBG)相结合。在传感测试中,光纤探头浸泡在100μM的罗丹明(R6G)水溶液中。然后用Labspec Aramis共聚焦拉曼光谱仪检索初步SERS结果。
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