The preparation and characterization of sulfonated poly (ether ether ketone) and Cellulose Acetate (SPEEK-CA) membrane in proton exchange membrane fuel cells (PEMFCs) by UV-crosslink technique

Nordiana Nabilla Ramly, A. Ali
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引用次数: 7

Abstract

A new series of cross linked proton conducting membranes consists of sulfonated poly (ether ether ketone) (SPEEK) and Cellulose Acetate (CA) has been developed over a wide range of compositions; SPEEK1−xCAx where x= 0.002,0.004, 0.006, 0.008, 0.01. The polymer electrolyte membrane is prepared by solution cast technique. The results indicate that the proton conductivity of the membranes increase with increasing solid proton conducting material. FTIR analysis shows that the cross linking reaction is performed successfully. All the results indicate that these cross-linked membranes based on SPEEK/CA show good prospect for the use as proton exchange membrane.
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质子交换膜燃料电池(pemfc)中磺化聚醚醚酮和醋酸纤维素(SPEEK-CA)膜的紫外交联制备及表征
一种由磺化聚醚醚酮(SPEEK)和醋酸纤维素(CA)组成的新型交联质子导电膜已被开发出来。SPEEK1−xCAx,其中x= 0.002,0.004, 0.006, 0.008, 0.01。采用溶液铸造法制备了聚合物电解质膜。结果表明,随着固体质子导电材料的增加,膜的质子电导率提高。FTIR分析表明,交联反应成功进行。结果表明,这些基于SPEEK/CA的交联膜作为质子交换膜具有良好的应用前景。
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