Long-term stability of gasochromic effect in TiO2:(W, Cr, Mo) thin film

J. Domaradzki, K. Baniewicz, M. Mazur, M. Pasierbek, T. Berlicki
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引用次数: 2

Abstract

Gasochromic thin films are used in the fields of gas sensing, smart windows and display industries. In this paper wettability and long-term stability of gasochromic effect of TiO2:(W, Cr, Mo) thin films have been investigated. Samples were deposited using high energy reactive magnetron sputtering process on Corning 7059 glass substrates. Contact angle, critical surface tension and surface free energy were determined using Theta Lite tensiometer. Thin films revealed hydrophilic properties. Gasochromic effect was observed in ethanol vapor atmosphere in temperature of at least 200 °C. Bleaching of the thin films was obtained in an ambient atmosphere at 350 °C. Also, the coloration of the samples was entirely reversible.
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TiO2:(W, Cr, Mo)薄膜气致变色效应的长期稳定性
气致变色薄膜广泛应用于气敏、智能窗和显示等领域。本文研究了TiO2:(W, Cr, Mo)薄膜的润湿性和气致变色效应的长期稳定性。采用高能反应磁控溅射工艺在康宁7059玻璃衬底上沉积样品。使用Theta Lite张力计测定接触角、临界表面张力和表面自由能。薄膜表现出亲水性。在温度至少为200℃的乙醇蒸气气氛中观察到气致变色效应。在350°C的环境气氛中获得了薄膜的漂白。而且,样品的颜色是完全可逆的。
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