INFLUENCE OF MINERAL ADDITIVES ON SULFATE STABILITY OF PORTLAND CEMENT

V. Gots, O. Kovalchuk, Yaroslav Oleksandrovych Hovdun
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Abstract

times comparing to the control composition. Use of fly ash is less effective from the cement grade point of view, but it provides 1.5 times better sulfate resistance comparing to Portland cement. Fly ash behavior separates on two directs – as a filler and as an aggregate. In general – as higher fly ash content, as higher sulfate resistance. The efficiency of increasing the sulfate resistance of cements with the use of active mineral additives of different types is considered. It was found that the maximum effect of increase of sulfate stability is observed with the use of combination of granular slag and fly ash in the composition of Portland cement systems, which is accompanied by an increase in sulfate stability of 2 times compared with the control composition. Portland cement systems with active mineral additives have been obtained, their sulfate stability is not inferior to traditional sulfate-resistant slag-portland cement. According to the test results it is shown possibility to obtain high sulfate corrosive resistance materials on Portland cement basis using blast furnace slag and fly ash admixtures. Service properties are meeting requirements of Ukrainian standards for common constructions.
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矿物添加剂对硅酸盐水泥硫酸盐稳定性的影响
与对照成分比较的次数。从水泥等级的角度来看,粉煤灰的使用效果较差,但与波特兰水泥相比,粉煤灰的抗硫酸盐性能提高了1.5倍。粉煤灰的性能在两个方向上分离——作为填料和作为集料。一般来说,粉煤灰含量越高,抗硫酸盐性越高。研究了不同类型的活性矿物添加剂对水泥抗硫酸盐性能的提高效果。研究发现,在硅酸盐水泥体系中使用颗粒渣与粉煤灰的组合对硫酸盐稳定性的提高效果最大,与对照组合相比,硫酸盐稳定性提高了2倍。已研制出含有活性矿物添加剂的硅酸盐水泥体系,其硫酸盐稳定性不逊于传统的抗硫酸盐矿渣硅酸盐水泥。试验结果表明,在硅酸盐水泥基础上采用高炉矿渣和粉煤灰掺合料制备高抗硫酸盐腐蚀材料是可行的。服务属性满足乌克兰普通建筑标准的要求。
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