Joseph J. Mihaly, D. Stewart, Tod A. Grusenmeyer, Alexis T Phillips, J. Haley, Thomas G. Gray
{"title":"Photoactive Gold Organometallics Bearing Substituted 2,7-Fluorenyl Moieties","authors":"Joseph J. Mihaly, D. Stewart, Tod A. Grusenmeyer, Alexis T Phillips, J. Haley, Thomas G. Gray","doi":"10.1109/RAPID49481.2020.9195695","DOIUrl":null,"url":null,"abstract":"Synthesis and optical characterization of organogold complexes bearing substituted fluorenyl moieties are described. Certain complexes are white-light emitters. Ancillary ligands modulate rate constants of radiative and nonradiative decay, and of intersystem crossing. Density-functional theory calculations indicate emission from excited states centered on the carbanionic ligands.","PeriodicalId":220244,"journal":{"name":"2020 IEEE Research and Applications of Photonics in Defense Conference (RAPID)","volume":"16 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2020-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"2020 IEEE Research and Applications of Photonics in Defense Conference (RAPID)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/RAPID49481.2020.9195695","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
Synthesis and optical characterization of organogold complexes bearing substituted fluorenyl moieties are described. Certain complexes are white-light emitters. Ancillary ligands modulate rate constants of radiative and nonradiative decay, and of intersystem crossing. Density-functional theory calculations indicate emission from excited states centered on the carbanionic ligands.
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