Secondary ion mass spectrometry study of organic and inorganic interfaces in methylammonium lead triiodide solar cells

Beatriz Montaño, José Juan Díaz, Y. Kudriavtsev, I. Cosme, S. Mansurova
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Abstract

The study of unstable interfaces in perovskite semiconductors requires crucial information on interfacial composition, chemical gradients, and impurity distribution. A versatile technique called TOF-SIMS can provide this information effectively. Solar cells employing methylammonium lead triiodide as the photoactive layer were fabricated, utilizing PEDOT:PSS or NiOx thin film as the hole transporting layer, and PCBM plus ZnO as the electron transporting layer. These inorganic and organic layers were deposited through magnetron sputtering and solution processing, respectively. To comprehensively examine each interface within the device structure, a detailed TOF-SIMS study was conducted.
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三碘化甲基铵铅太阳能电池中有机和无机界面的二次离子质谱研究
钙钛矿半导体中不稳定界面的研究需要关于界面组成、化学梯度和杂质分布的关键信息。一种称为TOF-SIMS的通用技术可以有效地提供这些信息。制备了以三碘化铅甲基铵为光活性层,以PEDOT:PSS或NiOx薄膜为空穴传输层,PCBM + ZnO为电子传输层的太阳能电池。这些无机层和有机层分别通过磁控溅射和溶液处理沉积。为了全面检查器件结构中的每个接口,进行了详细的TOF-SIMS研究。
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