Feasibility study of Improvement Experimental Measurement and Thermodynamic Modelling of Contaminants Effect on the Thermo-Mechanical Properties of Industrial Petroleum recycled plastics wastes

Khalid Farhod Chasib
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Abstract

The recycled plastics (RHDPE and RLDPE) were exposed to environment conditions for many years. Also the chemical contaminants had effects on the thermo-mechanical and other properties of these wastes. Then a weathering effect data is examined for both Iraqi and Foreign wastes on the thermo-mechanical and chemical properties (Tensile strength, modulus, elongation, impact and permeability).The different mathematical software model were applied to analysis these weathering – properties data in order to estimate which one or several among these properties had more effective by these weathering conditions such as (concentration of contaminant, time, temperature, thickness of specimen, length of spectra, basic property). The results shows that a multi-polynomial model has a best fit for most or several of properties to active weathering variables, also gave a vary residual and deviation than experimental analyzed data for both sources of wastes Iraqi and Foreign RHDPE and RLDPE. Also the results for thermo-mechanical and chemical properties prove that both tensile strength and modulus of elasticity thermo-mechanical properties and permeability / length of spectra chemical property were given a high quality of correction and fitting factor from 93-99 %, with less deviation and residual function was produced. And the results of RHDPE gave a best fit than RLDPE for most of checked analysis properties (thermo-mechanical and chemical properties).
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污染物对工业石油再生塑料废渣热机械性能影响的改进实验测量和热力学模型的可行性研究
再生塑料(RHDPE和RLDPE)暴露在环境条件下多年。此外,化学污染物对这些废物的热机械性能和其他性能也有影响。然后,对伊拉克和外国废物的热机械和化学特性(抗拉强度、模量、伸长率、冲击和渗透性)的风化效应数据进行了检查。应用不同的数学软件模型对这些风化性能数据进行分析,以估计在不同的风化条件下(污染物浓度、时间、温度、试样厚度、光谱长度、基本性能),哪一种或几种性能更有效。结果表明,多多项式模型能较好地拟合活性风化变量对RHDPE和RLDPE的大部分或部分性能的影响,并给出了与试验分析数据不同的残差和偏差。热力学性能和化学性能的结果表明,拉伸强度和弹性模量、热力学性能和透气性/光谱长度化学性能的校正和拟合系数在93% ~ 99%之间,偏差较小,产生的残余函数也较小。RHDPE的结果比RLDPE更适合于大多数检查的分析性能(热力学和化学性能)。
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