2D modeling of perovskite/Si tandem solar cell

Yegao Xiao, M. Lestrade, Zhiqiang Li, Zhanming S. Li
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Abstract

Based on a drift-diffusion simulator, 2D modeling of perovskite/Si tandem solar cell with tunnel junction is presented in this work. Current matching is explored between the two sub-cells. It is demonstrated that the basic tandem cell can achieve conversion efficiency as high as 28.27% with open-circuit voltage and short-circuit current density as 2.04 V and 16.18 mA/cm2 , respectively. As approaches for cell design optimization, the results are also analyzed versus the thickness and the minority carrier recombination lifetime of the perovskite layer. Efforts to incorporate coating, to consider texture effect for the bottom Si cell as well as to look for alternative electron transport layer for the top junction are also performed, presented and discussed. Efficiency as high as 36.40% is further projected.
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钙钛矿/硅串联太阳能电池的二维建模
基于漂移扩散模拟器,建立了具有隧道结的钙钛矿/硅串联太阳能电池的二维模型。探索两个子单元之间的电流匹配。结果表明,当开路电压为2.04 V,短路电流密度为16.18 mA/cm2时,基本串联电池的转换效率高达28.27%。作为电池设计优化的方法,结果也与钙钛矿层的厚度和少数载流子复合寿命进行了分析。本文还介绍和讨论了结合涂层、考虑底部硅电池的织构效应以及寻找顶部结的替代电子传输层的努力。预计效率最高可达36.40%。
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