Physico-chemical modeling of hidrothermal mineralization processes at Ni-Co-As (± U-Ag), Co-S-As (± Au-W), Cu-Co-As (± Sb-Ag) deposits.

V. Lebedev, A. Borovikov, L. Gushchina, I. S. Shabalin
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Abstract

A generalization of the results of the study of the composition of metal-bearing fluids of cobalt deposits of hydrothermal Genesis, formed in different geodynamic settings in connection with the formation of alkaline and alkaline-basite intrusions and dikes. To determine the physical and chemical parameters of ore deposition from fluid inclusions in minerals, both traditional and new instrumental methods of thermobarogeochemistry were used: thermo-and cryometry, RAMAN spectroscopy, concentration of ore and petrogenic elements in individual fluid inclusions were evaluated by LA-ICP-MS. The obtained results served as the basis for the study, the main task of which was the thermodynamic modeling of the conditions of joint transport and deposition of Co, Ni, Cu, Fe, Mg, Ca, Ag, Au, Bi, U, Pt and Pd C calculation of a number of equilibrium States of the hydrothermal system, the composition close to the natural ore-forming fluids. Physical and chemical factors of native deposits-gold, silver, platinum and palladium in the ores of such deposits are revealed. The obtained data can serve as a basis for the development of correct genetic models of ore-forming systems of cobalt deposits and contribute to solving the problems of their search.
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Ni-Co-As(±U-Ag)、Co-S-As(±Au-W)、Cu-Co-As(±Sb-Ag)矿床热液成矿过程物理化学模拟
热液成因钴矿床含金属流体组成研究结果的概括,这些矿床形成于不同地球动力学背景下,与碱性和碱性基岩侵入体和岩脉的形成有关。为了确定矿物中流体包裹体的成矿物理化学参数,采用了传统的热压地球化学仪器方法和新型热压地球化学仪器方法:测温法、拉曼光谱法、LA-ICP-MS法测定了单个流体包裹体中矿石和成岩元素的浓度。研究的主要任务是对Co、Ni、Cu、Fe、Mg、Ca、Ag、Au、Bi、U、Pt和Pd - C等元素的联合运移和沉积条件进行热力学模拟,计算热液系统的多种平衡状态,其组成接近天然成矿流体。揭示了该类矿床矿石中金、银、铂、钯等天然矿床的物理化学因素。所得数据可作为建立正确的钴矿床成矿系统成因模型的基础,并有助于解决找矿问题。
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