Moisture Uptake and Release by Plastic Molding Compoundsits Relationship to System Life and Failure Mode

D. W. Dycus
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引用次数: 5

Abstract

Plastic molding compounds show two major moisture uptake rates, one fast and one slow. The fast rate represents the moisture uptake mechanism that is responsible for moisture dependent failures in epoxy novolac plastics. It is felt that the fast rate represents transport through the organic epoxy matrix by hydrogen bonding. Silicone epoxy shows a much slower rate of moisture uptake after an initial induction period. The moisture dependent failure is therefore controlled by the slower rate in silicone epoxy. The slower rate is thought to be uptake by the silica filler matrix.
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塑料成型复合材料吸湿和释湿与系统寿命和失效模式的关系
塑料成型化合物表现出两种主要的吸湿率,一种快,一种慢。快速速率代表了吸湿机制,这是负责的水分依赖的失效在环氧树脂。可以认为,快速的速率代表了氢键通过有机环氧基的传输。在初始诱导期后,硅树脂的吸湿率要慢得多。因此,在硅树脂中,水分依赖的失效是由较慢的速率控制的。较慢的速率被认为是由二氧化硅填料基体吸收的。
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