Synthesis and characterization of La10Si6O27

E. Voinea, N. Cioateră, A. Barbu, A. Simioneascu, C. Spînu
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Abstract

Oxide ion conductors are an important group of materials which have been increasingly studied due to their applications in many devices of high technological interest, especially in Solid Oxide Fuel Cells (SOFC) which are efficient and environmentally friendly energy convertors. In this work we study an inexpensive, suitable and recyclable material with apatite structure. Lanthanum silicate with apatite type structure, La10Si6O27,was synthesized by two pathways: sol-gel and co-precipitation. The as-obtained powders were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) and Raman spectroscopy. Samples with different morphologies consisting of a mixture of phases were obtained.
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La10Si6O27的合成与表征
氧化物离子导体是一类重要的材料,由于其在许多高科技器件中的应用,特别是在固体氧化物燃料电池(SOFC)中作为高效和环保的能源转换器而受到越来越多的研究。本文研究了一种廉价、合适、可循环利用的磷灰石结构材料。采用溶胶-凝胶法和共沉淀法合成了具有磷灰石型结构的硅酸镧La10Si6O27。采用x射线衍射(XRD)、扫描电镜(SEM)和拉曼光谱对所得粉体进行了表征。得到了由不同相组成的不同形貌的样品。
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