Segregation and Phase Transitions in Grain Boundaries

B. Bokstein, A. Rodin, A. Itckovich, L. Klinger
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引用次数: 1

Abstract

The paper is devoted to some properties of grain boundaries: Segregation and concentration phase transitions – two important consequences of atomic interactions in grain boundaries. Except of a short description the Gibbs method of surface excesses and grain boundary segregation isotherms with the limited number of segregation sites in grain boundary, the paper concentrates on the effects of complexes formation, including thermodynamic and computer modeling, and concentration phase transition in the grain boundaries in systems with restricted solubility and intermediate compounds.
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晶界中的偏析与相变
本文讨论了晶界的一些性质:偏析和集中相变——晶界中原子相互作用的两个重要结果。除了简短地描述了Gibbs方法的表面过度和晶界偏析等温线在晶界上的偏析位点数量有限之外,本文还集中讨论了配合物形成的影响,包括热力学和计算机建模,以及在具有限制溶解度和中间化合物的体系中晶界的浓度相变。
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