Identification of Construction Sludge Generated by Earth Drilling

Hitomi S. Kikkawa, Kento Kumisaka, R. Sugita, K. Tsuge
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Abstract

Earth drilling is a method of making trenches for constructing piles. In this method, bentonite slurry is used to protect the porous wall during the trench excavation. The sludge from this method is defined as industrial waste under Japanese law and must be treated with an appropriate method. Nevertheless, some companies dispose of construction sludge illegally. However, there are no analytical methods for identifying bentonite sludge and it is unknown whether identification is possible. To identify sludge, bentonite must be detected in suspicious soils, but smectite clay, which is the main component of bentonite, is often contained in soil, and it is unknown whether the smectite in soil interferes with detection of bentonite from sludge.To detect bentonite in construction sludge, we analyzed soils spiked with bentonite at various concentrations using X-ray diffraction. We also examined construction sludge from earth drilling with or without HCl treatment. The bentonite peak was observed in all spiked samples, even when the bentonite concentration was 20% and the soil contained smectite. In construction sludge, bentonite peaks were observed without HCl treatment; however, they were smaller than expected. HCl treatment removed the chlorite peak, which was near that of bentonite, allowing for easier identification of bentonite peaks. We demonstrated that the construction sludge could be detected by identifying bentonite. This was a pilot study to identify industrial waste and provided new insights into the forensic analysis of environmental crime samples.
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土方钻井产生的建筑污泥的识别
钻土是一种挖沟造桩的方法。该方法在基坑开挖过程中,采用膨润土浆料对多孔壁进行保护。根据日本法律,这种方法产生的污泥被定义为工业废物,必须用适当的方法处理。然而,一些公司非法处理建筑污泥。然而,目前还没有识别膨润土污泥的分析方法,也不知道是否有可能进行识别。要识别污泥,必须在可疑土壤中检测到膨润土,但土壤中往往含有膨润土的主要成分蒙脱石粘土,土壤中的蒙脱石是否会干扰污泥中膨润土的检测尚不清楚。为了检测建筑污泥中的膨润土,我们使用x射线衍射分析了不同浓度的膨润土。我们还检查了土方钻井产生的建筑污泥,无论是否进行了HCl处理。即使在膨润土浓度为20%且土壤中含有蒙脱石时,在所有加样中均观察到膨润土峰。在建筑污泥中,未经HCl处理的膨润土峰出现;然而,它们比预期的要小。HCl处理去除了与膨润土相近的绿泥石峰,便于膨润土峰的识别。我们证明了可以通过识别膨润土来检测建筑污泥。这是一项鉴定工业废物的试点研究,并为环境犯罪样本的法医分析提供了新的见解。
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Identification of Construction Sludge Generated by Earth Drilling
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