Polymers with benzylidene fragment for nonlinear optical application

V. Smokal, B. Derkowska, R. Czaplicki, O. Krupka, A. Kolendo, B. Sahraoui
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Abstract

Oxazalone and thiohydantoin derivatives were synthesized and their physicochemical properties are determined by absorption, fluorescence, fluorescence excitation and HNMR spectroscopies. The polymerization was carried out in DMF with AIBN as initiator. The products of polymerization were characterized by HNMR. The third order nonlinear optical properties of oxazolone and thiohydantoin containing compounds have been investigated in solutions using degenerate four wave mixing (DFWM) method at 532 nm.
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含苄基片段聚合物的非线性光学应用
合成了恶沙酮和硫代海因衍生物,并通过吸收光谱、荧光光谱、荧光激发光谱和核磁共振光谱测定了它们的理化性质。以AIBN为引发剂,在DMF中进行聚合反应。聚合产物经核磁共振表征。采用简并四波混频(DFWM)方法研究了含恶唑酮和硫代海因化合物在532 nm下的三阶非线性光学性质。
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