S

Ayhan Özmen, R. Tapramaz, Fevzi Köksal, H. Yüksel
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Abstract

The Electron Spin Resonance(ESR) of iminoxy radicals trapped in gamma-irradiated isonitroseacetophenone and phenylglioxime single crystals have been studied. It has been understood that iminoxy radicals trapped in these crystals is isomeric iminoxy radicals. In addition site splitings have been observed for both of crystals for every radicals, principal components of the g and hyperfine tensors of N and proton; distribution spin density of unpaired electron in radicals; s and p charecters of spin density on the nitrogen, and CNO bond angle have been calculated.
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研究了γ辐照异硝基苯乙酮和苯酰肟单晶中亚氧基自由基的电子自旋共振(ESR)。在这些晶体中捕获的亚氧基是同分异构体亚氧基。此外,在这两种晶体中,每个自由基、g的主成分以及N和质子的超精细张量都发生了位点分裂;自由基中未配对电子的自旋密度分布计算了氮上自旋密度的s和p特征,以及CNO键角。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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