Catalytic Hydrodehalogenation of Haloarenes with Hydrogen and Hydrogen-Containing Compounds: A Review

IF 0.7 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Theoretical and Experimental Chemistry Pub Date : 2023-11-10 DOI:10.1007/s11237-023-09775-4
V. Sh. Saberov, G. F. Rayenko, A. S. Avksentiev, L. M. Vakhitova, N. I. Korotkikh
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Abstract

New catalytic methods for the hydrodehalogenation of haloarenes with hydrogen and hydrogen-containing reagents (metal and non-metal hydrids, organic hydrogen-containing compounds, etc.), which are essential for fine organic synthesis and neutralization of toxic production waste and persistent organic pollutants. The paper focuses on such catalysts as complexes of stable heterocyclic carbenes, transition metals, and nanosized metal particles and their composites, as the most promising for industrial chemistry. Catalysts with particularly high efficiency have been highlighted.

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氢及含氢化合物催化卤代芳烃加氢脱卤研究进展
用氢和含氢试剂(金属和非金属氢化物、有机含氢化合物等)催化卤代芳烃加氢脱卤的新方法,对精细有机合成和中和有毒生产废弃物和持久性有机污染物至关重要。本文重点介绍了稳定杂环羰基配合物、过渡金属、纳米级金属颗粒及其复合材料等催化剂,它们是工业化学中最有前途的催化剂。效率特别高的催化剂得到了重视。
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来源期刊
Theoretical and Experimental Chemistry
Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.60
自引率
10.00%
发文量
30
审稿时长
6-12 weeks
期刊介绍: Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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