{"title":"A model of chronoamperometry of a two electrons electro-deposition reaction with the adsorption of intermediate","authors":"Milivoj Lovrić","doi":"10.5599/jese.2026","DOIUrl":null,"url":null,"abstract":"A single step chronoamperometry of reversible reactions complicated by the intermediate adsorption and the product deposition on inert electrodes is compared theoretically with an initial state of a simple two electrons electro-deposition. If the intermediate is highly unstable, these two mechanisms are similar, but the mechanism with successive electron transfers is needed to explain the responses appearing generally. The stability of intermediate depends on standard potentials of two steps and on the strength of adsorption. Two limiting cases are analysed and the difference between them is described.","PeriodicalId":15660,"journal":{"name":"Journal of Electrochemical Science and Engineering","volume":"22 7","pages":"0"},"PeriodicalIF":2.9000,"publicationDate":"2023-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Electrochemical Science and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5599/jese.2026","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
Abstract
A single step chronoamperometry of reversible reactions complicated by the intermediate adsorption and the product deposition on inert electrodes is compared theoretically with an initial state of a simple two electrons electro-deposition. If the intermediate is highly unstable, these two mechanisms are similar, but the mechanism with successive electron transfers is needed to explain the responses appearing generally. The stability of intermediate depends on standard potentials of two steps and on the strength of adsorption. Two limiting cases are analysed and the difference between them is described.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
