Study on the effect of binder content on the cook-off response characteristics of HMX-based PBX

IF 1.7 3区 材料科学 Q3 CHEMISTRY, APPLIED Journal of Energetic Materials Pub Date : 2023-11-01 DOI:10.1080/07370652.2023.2275203
Bing-Xv Qiao, Zeng-You Liang, Tong-Tong Zhou, Hao-Qiang Gao, Xiao-Ru Ji, Chao-Hui Tong
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Abstract

ABSTRACTThe cook-off tests and numerical simulations were carried out on the HMX-based PBX to study the influence of binder content on the cook-off response characteristics of PBX. The temperature change history of the powder column was obtained, and the change in temperature due to crystal transformation was observed. The response temperature of the column was obtained. In addition, the results showed that the response temperature of the PBX decreased with the increase of the binder content. Under the same binder content, the damage to a slow cook-off bomb was higher than that of a fast cook-off bomb. In the fast cook-off test, the cook-off response temperature of the HMX-based PBX was 310.3 ℃~322.5 ℃ The critical Estane content when the response grade was combustion was 5%. Under the slow cook-off conditions, the response temperature was 260.8 ℃ ~278.6 ℃. The critical Estane content when the response grade was combustion was 7%. Numerical simulation results proved that adding binder would cause a temperature drop due to the crystal transformation. The higher the binder content, the more noticeable this phenomenon was. The maximum error between the numerical simulation and the test results did not exceed 6.5%. KEYWORDS: Binder contentcook-off testscrystal transformationHMX-based PBXnumerical simulation Disclosure StatementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors would like to acknowledge [Shanxi Science and Technology Department] grant number [20210302124210] to provide funds for conducting experiments.
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粘结剂含量对hmx基PBX烧退响应特性的影响研究
摘要对基于hmx的PBX进行了退烧试验和数值模拟,研究了粘结剂含量对PBX退烧响应特性的影响。得到了粉末柱的温度变化历史,并观察了结晶转变引起的温度变化。得到了色谱柱的响应温度。此外,实验结果表明,随着粘结剂含量的增加,PBX的响应温度降低。在黏合剂含量相同的情况下,慢速烧退弹的损伤要高于快速烧退弹。在快速熄火试验中,hmx基PBX的熄火响应温度为310.3℃~322.5℃,响应等级为燃烧时的临界Estane含量为5%。在慢熟条件下,反应温度为260.8℃~278.6℃。反应等级为燃烧时,临界Estane含量为7%。数值模拟结果表明,加入粘结剂会引起结晶转变导致温度下降。粘结剂含量越高,这种现象越明显。数值模拟与试验结果的最大误差不超过6.5%。关键词:粘结剂内容煮掉测试晶体转换基于hmx的pbx数值模拟披露声明作者未报告潜在的利益冲突。作者感谢山西省科学技术厅批准号[20210302124210]为实验提供资金。
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来源期刊
Journal of Energetic Materials
Journal of Energetic Materials 工程技术-材料科学:综合
CiteScore
5.70
自引率
4.80%
发文量
34
审稿时长
1.8 months
期刊介绍: The Journal of Energetic Materials fills the need for an international forum of scientific and technical interchange in the disciplines of explosives, propellants, and pyrotechnics. It is a refereed publication which is published quarterly. Molecular orbital calculations, synthetic and analytical chemistry, formulation, ignition and detonation properties, thermal decomposition, hazards testing, biotechnology, and toxicological and environmental aspects of energetic materials production are appropriate subjects for articles submitted to the Journal.
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