A two-fold interpenetrated Zn(II) organic framework based on mixed ligands: Synthesis, crystal structure, and properties

Abstract

A new zinc(II) metal organic framework has been obtained from the solvothermal assembly of 1,3,5-benzene tricarboxylate and 1,3-bis(imidazole)propane with zinc nitrate in DMAc–H 2 O (DMAc is N,N-dimethylacetamide), namely {[Zn 2 (μ 2 -OH)(1,3-BIP)(BTC)]·DMAc·2H 2 O} n (SNUT-6). The product is characterized by single-crystal and powder X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, and elemental analysis. The single-crystal X-ray diffraction reveals that SNUT-6 exhibits a 3D→3D two-fold interpenetrating framework. Furthermore, SNUT-6 demonstrates a highly efficient turn-off fluorescent detection ability for aniline in methanol and shows high sensitivity with a K sv value of 4.771 × 10 4 M −1 . It also shows excellent photocatalytic degradation performance for a three-dye molecular model: rhodamine b, methyl orange, and methyl blue.