Clays of the Republic of Belarus as engineering barriers for disposal of radioactive waste

N. A. Makovskaya, T. G. Leontieva, A. A. Baklay
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Abstract

Тhe criteria for compliance with which the properties and characteristics of clays from industrially exploited deposits of the Republic of Belarus were assessed in order to determine the possibility of their further use as part of the underlying screen of the radioactive waste disposal facility (RWDF) of the Belarusian NPP are defined. The performed experimental analysis of clay samples from 12 deposits of the Republic of Belarus showed that clays from the “Gorodnoye” deposits of the Brest region and the “Markovskoye” deposits of the Gomel region have optimal quality indicators for use as part of the RWDF engineering barrier (underlying screen). It has been established that these clay samples have high sorption properties for 137Cs and 85Sr radionuclides. The values of the degree of sorption of 137Cs and 85Sr radionuclides from an aqueous solution for the above clay samples are about 99 %, and the values of the quantitative indicator of sorption the coefficient of distribution of radionuclides – are about 104 l/kg. Over time, the fixation of 137Cs on the studied clay samples increases; as part of the underlying RWDF screen, these clays will be an effective anti-migration barrier to prevent the migration of radionuclides into the environment in the event of depressurization of radioactive waste packages.
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白俄罗斯共和国粘土作为处置放射性废物的工程屏障
Тhe对来自白俄罗斯共和国工业开采矿床的粘土的性质和特征进行了评估,以确定是否有可能进一步将其用作白俄罗斯核电站放射性废物处置设施的底层筛管的一部分。对来自白俄罗斯共和国12个矿床的粘土样品进行的实验分析表明,来自布列斯特地区的“Gorodnoye”矿床和戈梅利地区的“Markovskoye”矿床的粘土具有最佳的质量指标,可作为RWDF工程屏障(下垫屏障)的一部分。这些粘土样品对137Cs和85Sr放射性核素具有较高的吸附性能。上述粘土样品对137Cs和85Sr放射性核素水溶液的吸附度约为99%,吸附定量指标放射性核素分布系数-约为104 l/kg。随着时间的推移,137Cs在黏土样品上的固定增加;作为RWDF屏障的一部分,这些粘土将成为有效的防迁移屏障,在放射性废物包体降压的情况下防止放射性核素迁移到环境中。
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