Metallogenic mechanism of cobalt in the Zhuchong cobalt-rich skarn iron deposit in the Middle-Lower Yangtze River Valley Metallogenic Belt: Constrained by in-situ sulfur isotopes and zircon U-Pb dating

IF 1.7 3区地球科学 Q2 GEOLOGY 岩石学报 Pub Date : 2023-01-01 DOI:10.18654/1000-0569/2023.10.10

LIANG Xian, WANG FangYue, ZHOU TaoFa, WEI ChangShuai, ZHANG Long, GUO XianZheng, ZHANG Kun

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引用次数: 0

Abstract

钴作为关键战略性稀贵金属,主要以共伴生形式产于多类矿床中。其中,富钴矽卡岩型铁矿床是重要的具备开发潜力的矿床类型之一,但其钴的来源和富集机制不清。朱冲富钴矽卡岩型铁矿床位于长江中下游成矿带安庆-贵池矿集区,是成矿带内新近发现的首个大型矽卡岩型富铁矿床,其伴生的钴资源量达到了中等规模。同时,朱冲富钴矽卡岩型铁矿床中钴品位在长江中下游同类矿床中最高,达190g/t。本研究对朱冲富钴矽卡岩型铁矿床开展了成矿岩体锆石的U-Pb定年和矿床垂向(钻孔剖面)上黄铁矿原位硫同位素的空间变化分析。结果表明,两个深部隐伏的岩浆岩样品的锆石U-Pb年龄分别为139.6±1.0Ma和138.9±0.6Ma,为早白垩世。垂向上,黄铁矿硫同位素总体范围为+5.3‰~+13.9‰,δ³⁴S自上而下变化极大,且呈现较强的不均一性,明显不同于安庆铁铜矿的硫同位素组成。朱冲富钴矽卡岩铁矿自下而上矿化-蚀变分带中富钴磁铁矿矿体中黄铁矿δ³⁴S范围为5.3‰~10.0‰;近矿透辉石矽卡岩带中脉状黄铁矿δ³⁴S范围为12.1‰~13.9‰;蚀变闪长岩中脉状黄铁矿δ³⁴S范围为7.1‰~10.8‰;外带矽卡岩中脉状黄铁矿δ³⁴S范围为6.8‰~7.6‰;月山组含膏盐粉砂岩中黄铁矿δ³⁴S范围为12.0‰~12.7‰;最上部铜头尖组粉砂岩脉状黄铁矿δ³⁴S范围为6.1‰~7.8‰。朱冲富钴磁铁矿矿石中黄铁矿硫同位素介于月山岩体和月山组含膏盐粉砂岩硫同位素之间,矿石中硫同位素记录了两个端元的混合。长江中下游富钴矽卡岩型矿床(铁铜钴)成矿规模及品位的统计表明,钴矿化与铁铜矿床类型没有明显的对应关系,成矿热液中膏盐层硫的加入对钴矿化没有明显的影响,富钴矽卡岩型铁矿床钴主要源于岩浆热液,钴的沉淀主要受控于高温热液的演化。

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长江中下游成矿带朱冲富钴矽卡岩铁矿床钴成矿机制:原位硫同位素和锆石U-Pb定年约束

钴作为关键战略性稀贵金属,主要以共伴生形式产于多类矿床中。其中,富钴矽卡岩型铁矿床是重要的具备开发潜力的矿床类型之一,但其钴的来源和富集机制不清。朱冲富钴矽卡岩型铁矿床位于长江中下游成矿带安庆-贵池矿集区,是成矿带内新近发现的首个大型矽卡岩型富铁矿床,其伴生的钴资源量达到了中等规模。同时,朱冲富钴矽卡岩型铁矿床中钴品位在长江中下游同类矿床中最高,达190g/t。本研究对朱冲富钴矽卡岩型铁矿床开展了成矿岩体锆石的U-Pb定年和矿床垂向(钻孔剖面)上黄铁矿原位硫同位素的空间变化分析。结果表明,两个深部隐伏的岩浆岩样品的锆石U-Pb年龄分别为139.6±1.0Ma和138.9±0.6Ma,为早白垩世。垂向上,黄铁矿硫同位素总体范围为+5.3‰~+13.9‰,δ34S自上而下变化极大,且呈现较强的不均一性,明显不同于安庆铁铜矿的硫同位素组成。朱冲富钴矽卡岩铁矿自下而上矿化-蚀变分带中富钴磁铁矿矿体中黄铁矿δ34S范围为5.3‰~10.0‰;近矿透辉石矽卡岩带中脉状黄铁矿δ34S范围为12.1‰~13.9‰;蚀变闪长岩中脉状黄铁矿δ34S范围为7.1‰~10.8‰;外带矽卡岩中脉状黄铁矿δ34S范围为6.8‰~7.6‰;月山组含膏盐粉砂岩中黄铁矿δ34S范围为12.0‰~12.7‰;最上部铜头尖组粉砂岩脉状黄铁矿δ34S范围为6.1‰~7.8‰。朱冲富钴磁铁矿矿石中黄铁矿硫同位素介于月山岩体和月山组含膏盐粉砂岩硫同位素之间,矿石中硫同位素记录了两个端元的混合。长江中下游富钴矽卡岩型矿床(铁铜钴)成矿规模及品位的统计表明,钴矿化与铁铜矿床类型没有明显的对应关系,成矿热液中膏盐层硫的加入对钴矿化没有明显的影响,富钴矽卡岩型铁矿床钴主要源于岩浆热液,钴的沉淀主要受控于高温热液的演化。

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来源期刊

岩石学报 Earth and Planetary Sciences-Geochemistry and Petrology

CiteScore

3.60

自引率

22.20%

发文量

5997

审稿时长

6 months

期刊介绍： Acta Petrologica Sinica is an academic journal under the supervision of the Chinese Academy of Sciences and sponsored by the Chinese Society of Mineralogy, Petrology and Geochemistry and the Institute of Geology and Geophysics of the Chinese Academy of Sciences. The journal's publishing policy is to adhere to innovation, comprehensiveness, cutting-edge and orientation, advocate diversity and multi-school, rely on and unite the vast number of geoscientists across the country, explore the mysteries of nature, carry out extensive and in-depth basic theoretical research, promote the research and development of the field of earth science in my country, publish high-level scientific research results, and cultivate and train a large number of geoscientific research talents for my country. Acta Petrologica Sinica mainly reports on various disciplines related to the basic theory of petrology, including important basic theories and applied research results in magmatic petrology, metamorphic petrology, sedimentary petrology, petrology geotectonics, rock isotope chronology and isotope geochemistry, rock mineralization, and rock-forming mineralogy. At the same time, the journal also publishes review articles, problem discussions, academic trends and book reviews.