Characteristics Analysis of Chlorine Bypass Dust and Water- washed Residue

Sun-Mok Lee, Daekeun Lee, Jun-Ho Kil, Taewoo Lee, Hun Song, Woo Sung Yum
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Abstract

The main components of chlorine bypass dust are calcium, alkali, and chlorine. Chlorine components must be removed from chlorine bypass dust to enable its recycling as a cement raw material. Cement companies usually employ water-washing treatment to recover KCl from chlorine bypass dust. In this study, the chemical composition, mineral properties, and microstructure of the chlorine bypass dust and washed residues obtained from a 35,000 ton/year chlorine-bypass-dust-washing facility were analyzed to determine the feasibility of recycling the dust and its washed residues. The chlorine content of the dust decreased from 23.9% to 1.4% after washing, thus confirming the possibility of using the washed residues as a cement raw material. The CaO component increased from 22.4% to 49.8% whereas the K2O component decreased from 25.2% to 5.45%. The average particle diameter of the water-washed residues was 22.72 μm, which was significantly higher than that of the chlorine bypass dust before washing (12.13 μm). This result was attributed to the dissolution of chlorine compound particles measuring less than 1 μm in the chlorine bypass dust during washing.
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氯旁通粉尘及水洗渣特性分析
氯旁通粉尘的主要成分是钙、碱和氯。氯成分必须从氯旁路粉尘中去除,使其能够作为水泥原料回收利用。水泥公司通常采用水洗法从氯旁道粉尘中回收KCl。本研究分析了35000吨/年氯旁通洗尘装置氯旁通洗尘的化学成分、矿物性质和微观结构,以确定回收利用该装置氯旁通洗尘的可行性。洗后粉尘氯含量由23.9%降至1.4%,证实了洗后残渣作为水泥原料的可能性。CaO组分由22.4%上升到49.8%,K2O组分由25.2%下降到5.45%。水洗后残留物的平均粒径为22.72 μm,显著高于水洗前氯旁通粉尘的平均粒径(12.13 μm)。这是由于洗涤过程中氯旁路粉尘中溶解了小于1 μm的氯化合物颗粒所致。
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