Priyabrata Mukhi, Mukesh Kumar Nayak, Anuradha Mohanty, Sujit Roy
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引用次数: 0
Abstract
Novel Pd-Sn bimetallic nanoparticles have been synthesized using the wet chemical technique. The nanoparticles show excellent catalytic activity in oxidizing secondary benzyl alcohol to the corresponding carbonyl in water as the solvent without any additive. It also withstood multiple cycles without loss of activity. Preliminary kinetic studies indicate a β-hydride elimination mechanism.
Graphical abstract
A bench-friendly wet-chemical method is designed to synthesize Pd-Sn bimetallic nanoalloys characterized by PXRD, FESEM, HRTEM, UV-Vis, FT-IR, EDAX, and ICP-OES. The nanoalloy is highly dispersible in water and catalyzes the oxidation of secondary alcohols in water with high TOF.
期刊介绍：
Journal of Chemical Sciences is a monthly journal published by the Indian Academy of Sciences. It formed part of the original Proceedings of the Indian Academy of Sciences – Part A, started by the Nobel Laureate Prof C V Raman in 1934, that was split in 1978 into three separate journals. It was renamed as Journal of Chemical Sciences in 2004. The journal publishes original research articles and rapid communications, covering all areas of chemical sciences. A significant feature of the journal is its special issues, brought out from time to time, devoted to conference symposia/proceedings in frontier areas of the subject, held not only in India but also in other countries.
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