The Low-Temperature Plasma Effect of Dielectric Barrier Discharge on Physicochemical and Process Properties of Natural Iron Sulfides

IF 0.7 4区 工程技术 Q4 MINING & MINERAL PROCESSING Journal of Mining Science Pub Date : 2023-11-29 DOI:10.1134/s1062739123040129
V. A. Chanturia, I. Zh. Bunin, M. V. Ryazantseva
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Abstract

The authors describe the integrated studies into the influence exerted by nonequilibrium low-temperature plasma of dielectric barrier discharge in air under normal conditions and pressure on the acid-base, adsorption and flotation properties of natural iron sulfides (pyrite and arsenopyrite). The studies aimed to correlate the plasmachemical treatment parameters with the physicochemical and process properties of sulfide minerals. Using the Hammet indicator method, it is found that plasma treatment strengthens acceptor properties and weakens electron donor properties of pyrite surface, as well as weakens acceptor properties of arsenopyrite. Adsorptive properties of pyrite relative to the electron-donor butyl xanthate grow, and, as a consequence, flotation activity of the mineral improves. In case of arsenopyrite, the adsorptive properties and flotation activity decrease. It is shown that the low-temperature plasma pretreatment of minerals reduces arsenic yield in flotation froth by 10–11% at the reduced arsenic content of concentrate by 0.71–0.78%.

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介质阻挡放电低温等离子体对天然硫化铁理化及工艺性能的影响
摘要本文综合研究了常温和压力下介质阻挡放电非平衡低温等离子体对天然硫化铁(黄铁矿和毒砂)的酸碱、吸附和浮选性能的影响。研究的目的是将等离子体处理参数与硫化矿物的物理化学和工艺性质联系起来。采用Hammet指示剂法,发现等离子体处理增强了黄铁矿表面的受体性质,减弱了黄铁矿表面的电子给体性质,同时削弱了毒砂的受体性质。相对于电子供体丁基黄药,黄铁矿的吸附性能提高,因此,矿物的浮选活性提高。当含毒砂时,吸附性能下降,浮选活性降低。结果表明,在精矿砷含量降低0.71 ~ 0.78%的情况下,矿物低温等离子体预处理可使浮选泡沫中的砷收率降低10 ~ 11%。
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来源期刊
Journal of Mining Science
Journal of Mining Science 工程技术-矿业与矿物加工
CiteScore
1.70
自引率
25.00%
发文量
19
审稿时长
24 months
期刊介绍: The Journal reflects the current trends of development in fundamental and applied mining sciences. It publishes original articles on geomechanics and geoinformation science, investigation of relationships between global geodynamic processes and man-induced disasters, physical and mathematical modeling of rheological and wave processes in multiphase structural geological media, rock failure, analysis and synthesis of mechanisms, automatic machines, and robots, science of mining machines, creation of resource-saving and ecologically safe technologies of mineral mining, mine aerology and mine thermal physics, coal seam degassing, mechanisms for origination of spontaneous fires and methods for their extinction, mineral dressing, and bowel exploitation.
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