Dielectric Properties of Ni-Co Nanoferrites Synthesized using Green Synthesis Process

Neetu Dhanda, P. Thakur, A. Thakur
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Abstract

A series of nickel doped cobalt (NixCo1-xFe2O4, x=0.0 to 1.0) were successfully synthesized using green synthesized process. Tensile strain of all positive slope samples observed from the W-H (Williamson Hall) plot. It was discovered that as Ni-substitution increased, the dielectric constant (є’) increased from 148.07 to 243.62. Conversely, when the amount of Ni-substitution increases, the dielectric loss (tan δ from 0.23 to 0.05), imaginary part (є’’ from 98.81 to 17.87), and ac conductivity (σac from 1.62 to 0.15) all decreases at 1MHz frequency. The purpose of current work is to investigate Williamson Hall effect and dielectric properties to find out the effects of nickel doping on the vibrational mode and crystal structure of cobalt ferrite. This demonstrates that when Ni-substitution increases, energy losses at high frequencies decrease. Dielectric constant and ac conductivity, of all samples act in accordance with Koop's theory, the Maxwell-Wagner polarization procedure, and electron hopping This makes them suitable materials for high-frequency applications
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采用绿色合成工艺合成的镍钴纳米铁氧体的介电性能
采用绿色合成方法成功合成了一系列镍掺杂钴(NixCo1-xFe2O4, x=0.0 ~ 1.0)。从W-H (WilliamsonHall)图中观察到的所有正斜率样品的拉伸应变。发现随着ni取代量的增加,介电常数(n′)从148.07增加到243.62。相反,随着ni取代量的增加,在1MHz频率下,介质损耗(tan δ从0.23增加到0.05)、赝部(n′从98.81增加到17.87)和交流电导率(σac从1.62增加到0.15)均降低。本工作的目的是研究Williamson Hall效应和介电性能,以了解镍掺杂对钴铁氧体的振动模式和晶体结构的影响。这表明,当镍取代增加时,高频能量损失减少。所有样品的介电常数和交流电导率都符合koop理论,麦克斯韦-瓦格纳极化过程和电子跳变,这使它们成为高频应用的合适材料
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来源期刊
Current Materials Science
Current Materials Science Materials Science-Materials Science (all)
CiteScore
0.80
自引率
0.00%
发文量
38
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