Obtaining triplet-triplet absorption spectra and triplet lifetimes of long-lived molecules with a UV-Visible spectrophotometer

Tiago Palmeira , David S. Conceição , Diana P. Ferreira , Carla C. Ferreira , Luís F. Vieira Ferreira , Mário N. Berberan-Santos
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Abstract

A simple method for obtaining triplet-triplet absorption (TTA) spectra and triplet state (T1) lifetimes of long-lived triplets is presented and demonstrated with the polycyclic aromatic hydrocarbon coronene (both normal and perdeuterated forms) in a polymer matrix at room temperature. The TTA spectra obtained with a camera flash and a spectrophotometer are noisier but otherwise identical to those obtained with a state-of-the-art flash photolysis apparatus. The triplet lifetimes obtained from transient absorption are identical to the phosphorescence lifetimes of the same samples.

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用紫外-可见分光光度计获取长寿命分子的三重-三重吸收光谱和三重寿命
本文介绍了一种获取长寿命三重态三重态吸收(TTA)光谱和三重态(T1)寿命的简单方法,并用室温下聚合物基体中的多环芳烃冠烯(正常和氚化形式)进行了演示。使用照相机闪光灯和分光光度计获得的 TTA 光谱噪音较大,但在其他方面与使用最先进的闪光灯光解设备获得的光谱完全相同。通过瞬态吸收获得的三重态寿命与相同样品的磷光寿命相同。
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