Preparation of Mo-impregnated mordenite catalysts for the conversion of refined kernel palm oil into bioavtur

W. Trisunaryanti, Triyono, Karna Wijaya, I. Kartini, S. Purwono, Rodiansono, A. Mara, Amsal Budiyansah
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Abstract

The research aims to study the effects of Mo metal embedded on H-Mordenite on its activity and selectivity of hydrodeoxygenation (HDO) for Refined Palm Kernel Oil (RPKO) into bioavtur. The RPKO was obtained from the results of degumming and bleaching process of palm kernel oil and then analyzed using Gas Chromatography-Mass Spectrometer (GC-MS). The impregnation of Mo metal was carried out by spraying using an ammonium heptamolybdate precursor solution ((NH4)6Mo7O24•4H2O) with an initial Mo metal content of 5, 10, and 15wt% of H-Mordenite to produce 5-Mo/Mor, 10-Mo/Mor, and 15-Mo/Mor. The 15-Mo/Mor catalyst produced the highest amount of liquid product (46.08wt%) with bioavtur yield of 43.19wt%. The usability test showed that 15-Mo/Mor catalyst still produced a good performance after three times of use in the RPKO feed HDO with the second and third run test liquid product of 34.82 and 46.14wt% respectively with bioavtur yield of 32.58 and 43.45wt%, respectively.
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制备用于将精炼棕榈仁油转化为生物柴油的钼浸莫代石催化剂
本研究旨在研究金属钼嵌入 H-莫代硝石对精炼棕榈仁油(RPKO)加氢脱氧生成生物柴油的活性和选择性的影响。精炼棕榈仁油(RPKO)是由棕榈仁油脱胶和漂白过程产生的,然后使用气相色谱-质谱仪(GC-MS)进行分析。金属钼的浸渍是通过喷洒七钼酸铵前驱体溶液((NH4)6Mo7O24-4H2O)进行的,初始金属钼含量分别为 5、10 和 15wt% 的 H-莫代硝石,生成 5-Mo/Mor、10-Mo/Mor 和 15-Mo/Mor。15-Mo/Mor 催化剂产生的液体产品量最高(46.08wt%),生物硫产量为 43.19wt%。可用性测试表明,15-Mo/Mor 催化剂在 RPKO 进料 HDO 中使用三次后,性能仍然良好,第二次和第三次运行测试的液体产品分别为 34.82 和 46.14wt%,生物硫收率分别为 32.58 和 43.45wt%。
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来源期刊
Communications in Science and Technology
Communications in Science and Technology Engineering-Engineering (all)
CiteScore
3.20
自引率
0.00%
发文量
13
审稿时长
24 weeks
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