Diclofenac analysis in natural waters using UV-visible absorption spectrometric method

IF 1.1 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Macedonian Journal of Chemistry and Chemical Engineering Pub Date : 2023-12-24 DOI:10.20450/mjcce.2023.2750
Jean-Marie Bakhoum, O. Mbaye, J. Bakhoum, M. D. Gaye-Seye, Clément Trellu, Coly Atanasse, J. Aaron
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Abstract

In this work, we developed an UV-visible (UV-VIS) absorption spectrometric method for the quantification of sodium diclofenac in natural waters. Several UV-VIS absorption method parameters were optimized. The maximum absorption wavelength was comprised between 276 and 292 nm, depending on the solvent, with molar absorption coefficients greater than 104 L mol-1 cm-1. The linearity of the UV-VIS calibration curves extended over one to three orders of magnitude, with correlation coefficients (R2) very close to unity. The low relative standard deviation (RSD)  values indicated a good reproducibility of the measurements. Analytical applications to natural waters yielded satisfactory results with average recovery rates between 94.7 and 99.1%.
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利用紫外可见吸收光谱法分析天然水体中的双氯芬酸
本研究建立了一种紫外-可见(UV-VIS)吸收光谱法,用于定量检测天然水体中的双氯芬酸钠。对紫外可见吸收光谱法的几个参数进行了优化。根据溶剂的不同,最大吸收波长在 276 至 292 nm 之间,摩尔吸收系数大于 104 L mol-1 cm-1。紫外-可见光谱校准曲线的线性范围在一至三个数量级之间,相关系数 (R2) 非常接近统一。较低的相对标准偏差 (RSD) 值表明测量结果具有良好的重现性。对天然水体的分析应用取得了令人满意的结果,平均回收率在 94.7% 到 99.1% 之间。
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来源期刊
CiteScore
1.60
自引率
20.00%
发文量
14
审稿时长
>12 weeks
期刊介绍: Macedonian Journal of Chemistry and Chemical Engineering (Mace­d. J. Chem. Chem. Eng.) is an official publication of the Society of Chemists and Technologists of Macedonia. It is a not-for-profit open acess journal published twice a year. The journal publishes ori­ginal scientific papers, short commu­ni­ca­tions, reviews and educational papers from all fields of chemistry, chemical engineering, food technology, biotechnology and material sciences, metallurgy and related fields. The papers pub­lished in the Journal are summarized in Che­mi­cal Abstracts.
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