Jewelry and ornamental concretions with fossils of the Republic of Kabardino-Balkaria. Mineral composition, gemological characteristics

D. A. Petrochenkov, E. Y. Baraboshkin
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Abstract

Background. Along with ammonites and septaries, concretions with fossils are increasingly being used as jewelry and ornamental materials in Russia. Such concretions are characterized by a wide range of sizes, as well as high decorative and technological properties, making them attractive materials for manufacturing diverse interior and jewelry products. The collection and processing of concretions with fossils was previously carried out in the Ulyanovsk region. In this paper, similar concretions found in the Republic of Kabardino-Balkaria are studied for the first time.Aim. Tо establish the stratigraphic position, mineral composition, and decorative and technological characteristics of concretions with fossils of jewelry and ornamental quality found in the Republic of Kabardino-Balkaria.Materials and methods. The collection sites of concretions with fossils and their stratigraphic position were studied. In total, 15 samples characterizing the main decorative and technological types were selected. Interior and jewelry items were manufactured from the concretions; typical samples were studied. A set of studies included the determination of luminescence (8 samples), microhardness (8 cycles), density (6 cycles), optical-petrographic analysis (3 sections), quantitative determination of mineral and chemical composition (2 samples), electron probe studies (2 samples).Results. Concretions with fossils of commercial quality are associated with lower Aptian deposits, representing marlstone with a large number of shells, mainly ammonites, and, to a lesser extent, bivalves. These comprise (wt %): calcite — 64.0, quartz — 18.7, microcline — 7.4, illite — 5.6, smectite — 2.7, kaolinite — 1.0, strontianite — 0.5, as well as traces of pyrite, apatite, albite, ilmenite, and goethite. Among the impurity elements, Sr in the amount of 0.0402 wt % is recorded.Conclusions. For the first time, the mineral and chemical (including micro-inclusions and impurity elements) composition of concretions with fossils of jewelry and ornamental quality are established. Factors determining their decorative and technological characteristics are identified. The possibility of using concretions with fossils for manufacturing a wide range of products, including jewelry, is shown. Concretions can be collected simultaneously with ammonites and septaries in river valleys without mining, thereby involving minimal costs and having no negative effect on the environment.
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含有卡巴尔达-巴尔卡尔共和国化石的珠宝和装饰凝块。矿物成分、宝石学特征
背景。在俄罗斯,除了氨虫和隔膜,含有化石的凝块也越来越多地被用作珠宝和装饰材料。这些凝块的特点是尺寸范围广、装饰性和技术性强,因此成为制造各种室内装饰和珠宝产品的极具吸引力的材料。此前,乌里扬诺夫斯克地区曾对含有化石的凝灰岩进行过采集和加工。本文首次研究了在卡巴尔达-巴尔卡尔共和国发现的类似凝块。确定在卡巴尔达-巴尔卡尔共和国发现的珠宝和装饰化石凝块的地层位置、矿物成分、装饰和工艺特征。对化石凝块的采集地点及其地层位置进行了研究。总共选择了 15 个样本,这些样本具有主要装饰和技术类型的特征。用凝灰岩制造了室内装饰和珠宝首饰;对典型样本进行了研究。一系列研究包括发光测定(8 个样本)、显微硬度测定(8 个周期)、密度测定(6 个周期)、光学摄谱分析(3 个切片)、矿物和化学成分定量测定(2 个样本)、电子探针研究(2 个样本)。含有商业质量化石的凝块与下古生代矿床有关,代表了含有大量贝壳的泥灰岩,主要是氨水母,其次是双壳类。其中包括(重量百分比):方解石-64.0、石英-18.7、微晶石-7.4、伊利石-5.6、埃山石-2.7、高岭石-1.0、锶铁矿-0.5,以及微量黄铁矿、磷灰石、白云石、钛铁矿和网纹石。在杂质元素中,锶的含量为 0.0402 wt %。首次确定了具有珠宝和观赏价值的化石凝块的矿物和化学成分(包括微包裹体和杂质元素)。确定了决定其装饰和技术特性的因素。说明了利用含化石的凝灰岩制造包括珠宝在内的各种产品的可能性。凝块可与氨虫和隔膜同时在河谷中采集,无需采矿,因此成本最低,对环境也没有负面影响。
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