Multifunctional barrier coating systems created by multilayer curtain coating

November 2023 Pub Date : 2023-12-01 DOI:10.32964/tj22.11.706
D. Ventresca, Benjamin Benz, David Eisenhauer, G. Welsch, Dustin Burton
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Abstract

Functional coatings are applied to paper and paperboard substrates to provide resistance, or a barrier, against media such as oil and grease, water, water vapor, and oxygen, for applications such as food packaging, food service, and other non-food packaging. Today, there is increasing interest in developing recyclable and more sustainable approaches for producing these types of packages. This paper focuses on water-based barrier coatings (WBBC) for oil and grease resistance (OGR), water, moisture vapor transmission rate (MVTR), and oxygen barrier performance. The main goal is to create coated systems that can achieve more than one barrier property using multilayer curtain coating (MLCC) in a single application step. One advantage is in optimizing coating material cost with the use of functional chemistry in confined layers where performance is balanced within the coating layered structure. This allows simultaneous application of layers of different polymer types in one step to achieve the appropriate performance needs for a given barrier application. This paper provides working examples of using MLCC to create coating structures with multiple barrier properties in a single application pass. Barrier polymers studied include styrene butadiene, styrene acrylate, starch-containing emulsions, and polyvinyl alcohol. The paper also shows the effect of increasing the pigment volume concentration with platy clay or fine ground calcium carbonate on MVTR and OGR barrier properties.
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通过多层帷幕涂层创建的多功能阻隔涂层系统
在纸和纸板基材上涂布功能性涂料,可以抵御或阻隔油脂、水、水蒸气和氧气等介质,用于食品包装、餐饮服务和其他非食品包装。如今,人们越来越关注开发可回收和更具可持续性的方法来生产这些类型的包装。 本文重点介绍水性阻隔涂料 (WBBC)的耐油脂性 (OGR)、耐水性、湿气透过率 (MVTR) 和氧气阻隔性能。主要目标是利用多层帷幕涂层 (MLCC),在单一应用步骤中创建可实现一种以上阻隔性能的涂层系统。其优势之一是通过在封闭层中使用功能性化学物质来优化涂层材料成本,从而在涂层分层结构中实现性能平衡。这样就可以在一个步骤中同时应用不同类型的聚合物层,以满足特定阻隔应用的性能需求。 本文举例说明了如何使用 MLCC 在一次涂敷过程中形成具有多种阻隔性能的涂层结构。研究的阻隔性聚合物包括丁二烯苯乙烯、丙烯酸苯乙烯、含淀粉乳液和聚乙烯醇。论文还展示了用板状粘土或细磨碳酸钙提高颜料体积浓度对 MVTR 和 OGR 阻隔性能的影响。
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