Selective Transformation of Isoeugenol to Licarin A using HKUST-1 Catalyst

Do Van Dang, Nguyen Kim Oanh, Dang Van Long, Le Thanh Son
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Abstract

The research delineated the utilization of Cu-MOF (HKUST-1) as a proficient heterogeneous catalyst for the selective transformation of isoeugenol to licarin A. The HKUST-1 was synthesized through a straightforward methodology and its structure was confirmed by various characterization employing a range of techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM) with Energy Dispersive X-ray analysis (EDX), and N2 adsorption/desorption. The catalyst exhibited outstanding catalytic efficacy in the selective oxidation of isoeugenol, resulting in a 75% yield of licarin A under mild conditions in the presence of TBHP. Furthermore, the catalyst demonstrated stability, retaining its activity after being reused at least four times without deterioration.
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利用 HKUST-1 催化剂将异丁香酚选择性转化为利卡灵 A
该研究利用 Cu-MOF(HKUST-1)作为异丁香酚选择性转化为地衣素 A 的高效异相催化剂。HKUST-1 是通过简单的方法合成的,其结构通过各种表征技术(包括 X 射线衍射 (XRD)、扫描电子显微镜 (SEM) 与能量色散 X 射线分析 (EDX),以及 N2 吸附/解吸)得到确认。该催化剂在异丁香酚的选择性氧化中表现出卓越的催化效能,在 TBHP 存在的温和条件下,地衣素 A 的产率达到 75%。此外,该催化剂还表现出了稳定性,在重复使用至少四次后,其活性仍未降低。
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