Effect of Borax-Boric Acid Treatment on Fire Resistance, Thermal Stability, Acoustic, and Mechanical Properties of Mycelium Bio Composites

Tom Anto, Rejeesh Charuvila Rajendran, Praveen Kosappallyillom Muraleedharan, E. Jayamani
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Abstract

Mycelium biocomposite materials have been established as a sustainable alternative to polystyrene in single use applications like packaging. However only little investigations are done on improving their resistance to fire and heat, which can find use in newer applications. This paper focuses on the development and characterization of a mycelium-based sawdust-coir pith biocomposite material treated with a combination of fire-retardant compounds (borax and boric acid). The outcomes of fire resistance tests, such as flammability, flame penetration and rate of burning demonstrated a significant improvement in values with respect to untreated samples. However, samples having 30% boron compounds by weight in it exhibited the best fire resistance properties. The thermal analysis of treated samples indicated that the presence of fire-retardant chemicals has not significantly affected their thermal stability. The glass transition temperature (Tg) of treated mycelium composite material was found to be 212.75 °C against a value of 207.78 °C for untreated samples. The fire retardant treated mycelium composite samples having 30% boron by weight in it, exhibited an average sound absorption coefficient of 0.38 compared with a sound absorption coefficient of 0.29 for polyurethane foam. The prepared mycelium biocomposite has a self-extinguishing nature and exceptional fire resistance capabilities with an LOI value of 50%. The mechanical testing revealed that the presence of fire-retardant chemicals has significantly improved the flexural properties. However, only a marginal increase was visible in the compression strength of mycelium biocomposites.
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硼砂-硼酸处理对菌丝体生物复合材料耐火性、热稳定性、声学和机械性能的影响
在包装等一次性应用中,菌丝体生物复合材料已被确定为聚苯乙烯的可持续替代品。然而,在提高其耐火和耐热性方面却鲜有研究,而这种材料可用于更新的应用领域。本文的重点是开发一种以菌丝体为基础、经阻燃化合物(硼砂和硼酸)组合处理的锯屑-糙米髓生物复合材料,并对其进行表征。耐火试验的结果,如可燃性、火焰穿透性和燃烧速率,与未经处理的样品相比,都有显著提高。不过,硼化合物含量为 30% 的样品具有最佳的耐火性能。对处理过的样品进行的热分析表明,阻燃剂的存在并未对其热稳定性产生重大影响。经处理的菌丝复合材料的玻璃化转变温度(Tg)为 212.75 ℃,而未经处理的样品的玻璃化转变温度为 207.78 ℃。经阻燃处理的菌丝复合材料样品中含有 30% 重量的硼,其平均吸音系数为 0.38,而聚氨酯泡沫的吸音系数为 0.29。制备的菌丝体生物复合材料具有自熄性和优异的耐火能力,其 LOI 值为 50%。机械测试表明,阻燃剂的存在明显改善了挠曲性能。不过,菌丝体生物复合材料的抗压强度仅略有提高。
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来源期刊
Applied Science and Engineering Progress
Applied Science and Engineering Progress Engineering-Engineering (all)
CiteScore
4.70
自引率
0.00%
发文量
56
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