Development of novel composite polydecylmethylsiloxane hollow fiber membranes on highly permeable polysulfone support for С2+/С1 separation

D. Matveev, E. Grushevenko, Yu. I. Matveeva, V. Vasilevsky, I. Borisov
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Abstract

A novel composite hollow fiber membrane has been developed for the separation of C2+ hydrocarbons from their mixture with methane. A high-performance porous polysulfone hollow fiber support was fabricated. Polydecylmethylsiloxane (PDecMS) and polydimethylsiloxane (PDMS) were used as a thin selective layer. Comparison of the results of separation of binary mixture of CH4 and C4H10 using PDecMS/PSF and PDMS/PSF membranes showed that for the PDecMS/PSF module the specific retentate flux and n-butane concentration in the permeate are 1.7 times higher and energy consumption is 9 times lower.
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在高渗透性聚砜载体上开发用于С2+/С1分离的新型复合聚癸基甲基硅氧烷中空纤维膜
开发了一种新型复合中空纤维膜,用于从 C2+ 碳氢化合物与甲烷的混合物中分离碳氢化合物。制造出了一种高性能多孔聚砜中空纤维支架。聚癸基甲基硅氧烷(PDecMS)和聚二甲基硅氧烷(PDMS)被用作薄选择层。比较使用 PDecMS/PSF 和 PDMS/PSF 膜分离 CH4 和 C4H10 二元混合物的结果表明,PDecMS/PSF 膜组件的比截留通量和渗透液中的正丁烷浓度高 1.7 倍,能耗低 9 倍。
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