APPLICATION OF BISMUTHATE GLASSES AS A SUBSTRATE FOR GAS SENSORS

V. A. Kjutvitsky, I. A. Romanova, E. V. Mironova, V. V. Borisova, O. I. Ostanina, F. N. Karashevtsev
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Abstract

The synthesis of bismuth-borate glasses was carried out Composition (mass content, %): 70 Bi2O3, 2 GeO2, 25 B2O3, 3 MoO3; 70 Bi2O3, 17 GeO2, 10 B2O3, 3 MoO3 and bismuth glasses. Composition (mass content, %): 80 Bi2O3, 4 GeO2, 5 MoO3, 11 SiO2; 80 Bi2O3, 8 GeO2, 8,5 SiO2, 3,5 MoO3. Processes have been developed for forming a layer based on glass receptors using the method of ultrasonic spraying of interacting components and applying a water-insoluble polymer film obtained by a chemical reaction between a poly-N,N-dimethyl-3,4-dimethylenepyrrolidinium chloride polymer and a modifier potassium hexacyanoferrate (II). The sensors obtained on the basis of glasses make it possible to determine the content of hydrogen sulfide and water vapor in the air with an error of 2 – 4 %.
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铋酸玻璃作为气体传感器基底的应用
铋硼玻璃的合成是在以下条件下进行的: 70 Bi2O3, 2 GeO2, 25 B2O3, 3 MoO370 Bi2O3、2 GeO2、25 B2O3、3 MoO3;70 Bi2O3、17 GeO2、10 B2O3、3 MoO3 和铋玻璃。成分(质量含量,%):80 Bi2O3、4 GeO2、5 MoO3、11 SiO2;80 Bi2O3、8 GeO2、8.5 SiO2、3.5 MoO3。已开发出利用超声波喷涂相互作用成分的方法,在玻璃受体的基础上形成一层,并涂上由聚-N,N-二甲基-3,4-二亚甲基吡咯烷氯化物聚合物和改性剂六氰基铁酸钾(II)发生化学反应而得到的不溶于水的聚合物膜的工艺。利用这种玻璃制成的传感器可以测定空气中硫化氢和水蒸气的含量,误差在 2 - 4 % 之间。
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