OLIVINE-BASED SORBENTS FOR REMOVAL OF HEAVY METALS

S. Hayrapetyan, M. S. Hayrapetyan, H. H. Khachatryan
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Abstract

Inductively coupled plasma mass spectrometry (ISP-MS) and scanning electron microscope-X-ray fluorescence (SEM-XRF) methods were used for the investigation of olivine sorption properties. It has been shown, that olivine may be applied as a cheap and available material for the sorption of metals, including heavy metals, from wastewater. The comparatively low sorption capacity of olivine may pay off by its accessibility and cheapness. The mechanism of adsorption on the olivine surface may be described as the substitution of magnesium ions by cations of various metals. One trend can be fixed – when ionic radius of the metal cations increases, their sorption increases as well. However, it is hardly possible to tie everything with the ionic radius of metal ion. The specificity of each element is also important.
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用于去除重金属的橄榄石基吸附剂
在研究橄榄石的吸附特性时,采用了电感耦合等离子体质谱法(ISP-MS)和扫描电子显微镜-X 射线荧光法(SEM-XRF)。研究表明,橄榄石可以作为一种廉价且可用的材料,用于吸附废水中的金属,包括重金属。橄榄石的吸附能力相对较低,但由于其易得性和廉价性,橄榄石的吸附能力可能会得到补偿。橄榄石表面的吸附机理可以描述为各种金属的阳离子对镁离子的置换。可以确定的一个趋势是,当金属阳离子的离子半径增大时,其吸附力也会增大。不过,很难将所有情况都与金属离子的离子半径联系起来。每种元素的特异性也很重要。
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