Multifunctional finishes on photochromic microcapsule-printed cotton fabrics using titanium oxide nanoparticles

IF 1.3 4区 材料科学 Q3 CHEMISTRY, APPLIED Pigment & Resin Technology Pub Date : 2024-01-12 DOI:10.1108/prt-09-2023-0079
Gobikannan Tamilmani, Venkhatesan D., Santhosh P., Tamilselvan M., Suryappa Jayappa Pawar, Amin Hirenbhai Navinbhai
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Abstract

Purpose

This paper aims to study the combination of photochromic microcapsules, which use the ultraviolet (UV) rays for colour changing phenomena, and titanium oxide (TiO2) nanoparticles (NPs), which block the UV rays by their photocatalytic activity in the sunlight on the cotton fabric.

Design/methodology/approach

The TiO2 NPs mixed with photochromic printing paste are used for coating on cotton fabric and further curing is performed in a one-step process. The photochromic pigment printed fabric impregnated in a liquid solution is processed in a two-step process with two variables such as 1% TiO2 and 2% TiO2. The characterization of samples was done with a UV transmittance analyser, surface contact angle, antimicrobial test and fabric physical properties.

Findings

The UV protection of TiO2-treated photochromic printed fabric was high and gives the ultraviolet protection factor rating of 2,000 which denotes almost maximum blocking of UV rays. The antibacterial activity of the one-step samples shows the highest 36 mm zone of inhibition (ZOI) against S. aureus (gram-positive) and 32 mm ZOI against E. coli (gram-negative) bacteria. The one-step sample shows the highest static water contact angle of 118.6° representing more hydrophobicity, whereas the untreated fabric is fully wetted (0.4°). In two-step processes, as the concentration of TiO2 increased, the antibacterial activity, UV blocking and hydrophobicity became better.

Originality/value

This work achieves the multifunctional finishes by using photochromic microcapsules and NPs in a single process as a first attempt. The results inferred that one-step sample has achieved higher values in most of the tests conducted when compared to all other sample.

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利用纳米氧化钛在光致变色微胶囊印花棉织物上进行多功能整理
目的 本文旨在研究光致变色微胶囊(利用紫外线(UV)产生变色现象)与氧化钛(TiO2)纳米粒子(NPs)的结合,后者在棉织物上通过其在阳光下的光催化活性阻挡紫外线。浸渍在液体溶液中的光致变色颜料印花织物采用两步法处理,有两个变量,如 1% TiO2 和 2% TiO2。研究结果经 TiO2 处理的光致变色印花织物的紫外线防护能力很强,紫外线防护系数达到 2000,几乎最大程度地阻挡了紫外线。一步法样品的抗菌活性显示,对金黄色葡萄球菌(革兰氏阳性)的抑制区(ZOI)最大为 36 毫米,对大肠杆菌(革兰氏阴性)的抑制区(ZOI)最大为 32 毫米。一步法样品的静态水接触角最大,为 118.6°,表示疏水性更强,而未经处理的织物则完全湿润(0.4°)。在两步法中,随着 TiO2 浓度的增加,抗菌活性、紫外线阻隔性和疏水性都变得更好。 原创性/价值 本研究首次尝试在单一工艺中使用光致变色微胶囊和 NPs 实现多功能整理。结果表明,与所有其他样品相比,一步法样品在大多数测试中都达到了更高的数值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Pigment & Resin Technology
Pigment & Resin Technology 工程技术-材料科学:膜
CiteScore
2.80
自引率
21.40%
发文量
91
审稿时长
>12 weeks
期刊介绍: The journal looks at developments in: ■Adhesives and sealants ■Curing and coatings ■Wood coatings and preservatives ■Environmentally compliant coating systems and pigments ■Inks for food packaging ■Manufacturing machinery - reactors, mills mixing and dispersing equipment, pumps ■Packaging, labeling and storage ■Plus topical features and news on materials, coatings, industry people, conferences, books and so on ■Raw materials such as pigments, solvents, resins and chemicals ■Testing equipment and procedures
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