Evaluation of non-detonable canine training aids for explosives by headspace analysis and canine testing

IF 2.6 3区 医学 Q2 CHEMISTRY, ANALYTICAL Forensic Chemistry Pub Date : 2024-01-26 DOI:10.1016/j.forc.2024.100553
Lauryn E. DeGreeff , Christopher K. Katilie , Caitlin E. Sharpes , Michele N. Maughan , Jenna D. Gadberry , Patrick L. Nolan , Nathaniel Hall , Barry Magner , Eric M. Best , Emma Calabrese , Fantasia Whaley , Mark Hammond , Patricia E. Buckley
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Abstract

There is a need for non-detonable training aids to enable training of canines when access to true material is limited. A disadvantage of non-detonable training aids is the lack of third-party independent verification and validation to certify the efficacy of the aid to yield a detection capability to true material. The goal of this research is to guide the development of a pipeline for the evaluation of commercial off-the-shelf (COTS) or novel training aids by using both analytical analysis as well as canine olfactory testing. Headspace analysis was carried out for nitrated explosive training aids, RDX and PETN, as well as peroxide explosives, HMTD and TATP. Batch-to-batch reproducibility and usage lifetime mimicking operational usage, were also assessed for peroxide explosive aids. As a result of the analytical analysis, various issues were identified such as limitations of explosive component detection, presence of extraneous odors, dynamic headspaces, and both inter- and intra- batch variability. A single TATP training aid was selected to be tested in a proof-of-concept canine assessment which compared canines trained using true material in their ability to detect the training aid in question and a set of canines trained solely with a COTS training aid in their ability to detect true material. It took the canines collectively nearly 21 trials of exposures to true TATP before all canines trained with the non-detonable training aid were able to detect the true TATP with a 100% detection rate, highlighting the importance of analytical characterization of non-detonable training aids paired with canine validation studies.

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通过顶空气体分析和警犬测试评估爆炸物的非引爆警犬训练辅助工具
在获得真实材料的机会有限的情况下,需要非引爆训练辅助工具来训练警犬。非引爆训练辅助工具的一个缺点是缺乏第三方独立验证和确认,无法证明该辅助工具具有探测真实材料的能力。本研究的目标是通过分析分析和犬类嗅觉测试,为商用现成 (COTS) 或新型训练辅助工具的评估管道开发提供指导。对硝化炸药训练器材 RDX 和 PETN 以及过氧化物炸药 HMTD 和 TATP 进行了顶空分析。此外,还对过氧化物爆炸教具的批次间再现性和使用期限进行了评估,以模拟实际使用情况。分析结果发现了各种问题,如爆炸成分检测的局限性、外来气味的存在、动态顶空以及批次间和批次内的可变性。选择了一种 TATP 训练辅助工具,在警犬概念验证评估中对其进行测试,比较使用真实材料训练的警犬和仅使用 COTS 训练辅助工具训练的警犬检测真实材料的能力。在警犬集体暴露于真正的 TATP 近 21 次试验后,所有接受非引爆训练辅助工具训练的警犬才能检测到真正的 TATP,检测率达到 100%,这突出表明了非引爆训练辅助工具的分析特性与警犬验证研究相结合的重要性。
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来源期刊
Forensic Chemistry
Forensic Chemistry CHEMISTRY, ANALYTICAL-
CiteScore
5.70
自引率
14.80%
发文量
65
审稿时长
46 days
期刊介绍: Forensic Chemistry publishes high quality manuscripts focusing on the theory, research and application of any chemical science to forensic analysis. The scope of the journal includes fundamental advancements that result in a better understanding of the evidentiary significance derived from the physical and chemical analysis of materials. The scope of Forensic Chemistry will also include the application and or development of any molecular and atomic spectrochemical technique, electrochemical techniques, sensors, surface characterization techniques, mass spectrometry, nuclear magnetic resonance, chemometrics and statistics, and separation sciences (e.g. chromatography) that provide insight into the forensic analysis of materials. Evidential topics of interest to the journal include, but are not limited to, fingerprint analysis, drug analysis, ignitable liquid residue analysis, explosives detection and analysis, the characterization and comparison of trace evidence (glass, fibers, paints and polymers, tapes, soils and other materials), ink and paper analysis, gunshot residue analysis, synthetic pathways for drugs, toxicology and the analysis and chemistry associated with the components of fingermarks. The journal is particularly interested in receiving manuscripts that report advances in the forensic interpretation of chemical evidence. Technology Readiness Level: When submitting an article to Forensic Chemistry, all authors will be asked to self-assign a Technology Readiness Level (TRL) to their article. The purpose of the TRL system is to help readers understand the level of maturity of an idea or method, to help track the evolution of readiness of a given technique or method, and to help filter published articles by the expected ease of implementation in an operation setting within a crime lab.
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