Morphological and structural defect optimization in CsPbBr3 nanoparticle films for light-emitting electrochemical cells

Abstract

Crystalline and morphological defects in the perovskite film affect the operation of light-emitting devices. Thus, advanced and scalable fabrication techniques can improve device properties. In this work, we use slot-die coating at ambient conditions, followed by hot air drying, to produce CsPbBr₃ light-emitting electrochemical cells. We compare this method to spin-coating and analyze film morphology and optical properties. We reveal that annealing the film on a hot plate increases PLQY and Shockley-Read-Hole lifetime, but worsens film morphology. In contrast, hot air drying during deposition improves morphology but reduces photoluminescence. The slot-die coating shows better results for device fabrication. With InGa and Al top electrodes, we achieve luminance 8100 cd m⁻² and 2900 cd m⁻² at a 5 V bias, respectively.