A Study of the Magnetic Properties and Structure of Heusler Alloys Prepared by Arc-Melting Technique

Q2 Pharmacology, Toxicology and Pharmaceutics Science and Technology Indonesia Pub Date : 2024-01-22 DOI:10.26554/sti.2024.9.1.36-42
N. Khalefa
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Abstract

Heusler alloys were prepared in this study using the Arc-Melting method in which 30 g of the Arc-melting pure elements were combusted in an Argon arc furnace. Saturation magnetization, X-ray diffraction (XRD) analysis, and scanning electron microscope (SEM) were used to characterize the prepared alloys in terms of the compositions (Co2TiZ), where Z= Al, Ge, Sb are related IVB sub-group metals. In this work, the specimens containing Ge and Ti have fully Ferro magnetically order and L21 chemical structure with magnetism due to the magnetic moments attributed to the Co site. The Heusler alloys containing IIB or IVB sub-group metals such as Al, Ti, or Ge behave ferromagnetism, with the magnetic moments being attributed to the magnetic moments of the Co sites. Heusler alloys containing the group IVB element such as Sb exhibited vacant chemical effects with Co sites, and they also contain some paramagnetic compounds. Heusler alloys with Sb element exhibited paramagnetic behavior with vacant chemical order. Alloys demonstrate different magnetic properties as a result of temperature change and exchange interaction with atomic structure.
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电弧熔炼技术制备的 Heusler 合金的磁性能和结构研究
本研究采用弧熔法制备 Heusler 合金,即在氩弧炉中燃烧 30 克弧熔纯元素。饱和磁化、X 射线衍射 (XRD) 分析和扫描电子显微镜 (SEM) 被用来表征所制备合金的成分 (Co2TiZ),其中 Z= Al、Ge、Sb 是相关的 IVB 亚族金属。在这项工作中,含有 Ge 和 Ti 的试样具有完全铁磁有序和 L21 化学结构,其磁性归因于 Co 位点的磁矩。含有 IIB 或 IVB 亚族金属(如 Al、Ti 或 Ge)的 Heusler 合金具有铁磁性,磁矩归因于 Co 位点的磁矩。含有 IVB 族元素(如锑)的 Heusler 合金表现出与 Co 位点的空位化学效应,它们还含有一些顺磁化合物。含有锑元素的 Heusler 合金表现出顺磁性,具有空位化学效应。由于温度变化和原子结构的交换相互作用,合金表现出不同的磁性能。
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来源期刊
Science and Technology Indonesia
Science and Technology Indonesia Pharmacology, Toxicology and Pharmaceutics-Pharmacology, Toxicology and Pharmaceutics (miscellaneous)
CiteScore
1.80
自引率
0.00%
发文量
72
审稿时长
8 weeks
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