Chisa Takahara, Suzuka Iwasaki, Yusuke Miyake, T. Yumura, Hiroaki Imoto, K. Naka
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Abstract
The incorporation of heteroatoms serves as a potent tool for the development of advanced materials, and arsenic (As) has recently become increasingly popular in the field of conjugated molecules. However, the potential toxicity of As-containing materials upon disposal remains a concern. In this study, we propose a chemical recycling approach for the As in arsoles. The oxidative ring-opening reaction of arsoles proceeds efficiently under ultraviolet irradiation, leading to the production of phenylarsonic acid, a precursor of arsoles.
期刊介绍：
ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric.
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