Expansion mechanics of hydrogel-driven metamaterials with multiple deformation modes

IF 5.4 1区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY GIANT Pub Date : 2024-02-01 DOI:10.1016/j.giant.2024.100243
Ran Tao , Yuhan Guo , Jiahao Li , Junrong Luo , Qingsheng Yang , Yu Chen , Wenwang Wu
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Abstract

Hydrogel is widely employed in flexible electronics and soft robotics as soft mechanical material. Previous reports exploited the swelling properties of hydrogel to achieve large negative deformations, but few reports exhibit multiple deformation modes. This paper designs two-dimensional metamaterials that convert hydrogel swelling deformation into bending deformation, including positive/negative swelling, isotropic/anisotropic, and gradient/bending deformation modes. The regulation of hydrogel swelling on the negative expansion deformation of metamaterials is explored through the theoretical model and finite element analysis. The corresponding relationship between the microstructure deformation and the band gap change during the hydration process is obtained. Inspired by kirigami, we proposed a self-assembly model with substrate expansion-driven three-dimensional microstructure. The results show that the deformation modes of metamaterials may be interconverted through structural design. The band gap can be tuned by swelling deformation.

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具有多种变形模式的水凝胶驱动超材料的膨胀力学
水凝胶作为软机械材料被广泛应用于柔性电子和软机器人领域。以往的报道利用水凝胶的溶胀特性实现了较大的负变形,但很少有报道展示了多种变形模式。本文设计的二维超材料可将水凝胶的溶胀变形转化为弯曲变形,包括正/负溶胀、各向同性/各向异性和梯度/弯曲变形模式。通过理论模型和有限元分析,探讨了水凝胶膨胀对超材料负膨胀变形的调节作用。得出了水化过程中微结构变形与带隙变化之间的对应关系。受 kirigami 的启发,我们提出了基底膨胀驱动三维微结构的自组装模型。结果表明,超材料的变形模式可以通过结构设计相互转换。带隙可以通过膨胀变形来调整。
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来源期刊
GIANT
GIANT Multiple-
CiteScore
8.50
自引率
8.60%
发文量
46
审稿时长
42 days
期刊介绍: Giant is an interdisciplinary title focusing on fundamental and applied macromolecular science spanning all chemistry, physics, biology, and materials aspects of the field in the broadest sense. Key areas covered include macromolecular chemistry, supramolecular assembly, multiscale and multifunctional materials, organic-inorganic hybrid materials, biophysics, biomimetics and surface science. Core topics range from developments in synthesis, characterisation and assembly towards creating uniformly sized precision macromolecules with tailored properties, to the design and assembly of nanostructured materials in multiple dimensions, and further to the study of smart or living designer materials with tuneable multiscale properties.
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